Item type | Current library | Collection | Shelving location | Call number | Status | Date due | Barcode | Item holds | |
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BITS Pilani Hyderabad | 620 | General Stack (For lending) | 620.118 ZOP-I (Browse shelf(Opens below)) | Available | 42856 |
This thesis investigates the early ignition behaviour of polymer/clay nanocomposites, which are perceived as potential eco-friendly flame retardant systems. It examines the correlation between clay structural chemistry and high-temperature transformations with the clay-assisted decomposition of organic macromolecules. In particular, it investigates the unique effects of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays (smectite) on the combustion and thermo-oxidative decomposition of polyamide 6. The results indicate that metal ions present on/in montmorillonite platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 thermal decomposition. Lastly, a simple solution in the form of a physical coating on clay surface is proposed, based on the role of polymer–clay interfacial interaction.
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